论文标题
运动性诱导的相分离的动态和热力学起源
Dynamic and Thermodynamic Origins of Motility-Induced Phase Separation
论文作者
论文摘要
主动物质系统固有地超出平衡,并以微观量表打破详细的平衡(DB),表现出重要的集体现象,例如运动诱导的相位分离(MIPS)。在这里,我们介绍了一种粗粒映射方法,以探测密度 - 能量相空间中的DB破裂,这使我们能够基于非平衡电位和通量景观理论揭示MIP的动态和热力学起源。通过识别粗粒相空间中的可见概率通量来表现出非平衡性能的标志。 Remarkably, the flux for the system with the activity lower than the MIPS threshold tends to ``tear up" the single potential well of the uniform-density phase to create two wells of phases with different densities, presenting directly that the nonequilibrium flux is the dynamic origin of MIPS. Moreover, we find that the obtained entropy production rate (EPR) of the system undergoes a transition from nearly independent of activity to increasing proportionally as activity increases after单孔是“撕裂”,EPR缩放行为的过渡可能会提示MIPS在粗粒空间中的热力学起源。
Active matter systems are inherently out of equilibrium and break the detailed balance (DB) at the microscopic scale, exhibiting vital collective phenomena such as motility-induced phase separation (MIPS). Here, we introduce a coarse-grained mapping method to probe DB breaking in the density-energy phase space, which allows us to reveal the dynamic and thermodynamic origins of MIPS based on nonequilibrium potential and flux landscape theory. Hallmarks of nonequilibrium properties are manifested by identifying the visible probability flux in the coarse-grained phase space. Remarkably, the flux for the system with the activity lower than the MIPS threshold tends to ``tear up" the single potential well of the uniform-density phase to create two wells of phases with different densities, presenting directly that the nonequilibrium flux is the dynamic origin of MIPS. Moreover, we find that the obtained entropy production rate (EPR) of the system undergoes a transition from nearly independent of activity to increasing proportionally as activity increases after the single well is "teared up". The transition of EPR's scaling behavior might provide a hint of the thermodynamic origin of MIPS in the coarse-grained space. Our findings propose a new route to explore the nonequilibrium nature of active systems, and provide new insights into dynamic and thermodynamic properties of MIPS.