论文标题

星际碳一氧化碳(CO)冰类似物的密度和红外带强度

Density and infrared band strength of interstellar carbon monoxide (CO) ice analogues

论文作者

Díaz, Cristóbal González, Carrascosa, Hector, Caro, Guillermo M. Muñoz, Satorre, Miguel Ángle, Chen, Y. -J.

论文摘要

在模仿的星际条件下研究实验CO冰的动机得到了冰冷的谷物地幔中CO的大量CO气体丰度和无处不在的存在。在以纯冰形式辐射后,这种高度稳定的物种呈现有限的离子和光子诱导的化学作用,并有效的非热解。使用红外光谱,单个激光干扰和CO冰沉积期间的四极质量光谱法,CO冰密度的估计是沉积温度的函数。仅发现密度的较小变化。所提出的方法可用于在各种沉积温度下获得其他冰分的密度,前提是这些温度之一是已知的,这通常是与结晶形式相对应的温度。在14 K以下的沉积温度下,CO冰密度降低的明显趋势与最近发表的比色测量值一致。这项工作允许重新审视红外观测中CO冰柱密度所需的红外带强度的值,$ 8.7 \ times 10^{ - 18}〜{\ rm cm〜molecule}^{ - 1} $在20 K沉积温度下。

The motivation to study experimentally CO ice under mimicked interstellar conditions is supported by the large CO gas abundances and ubiquitous presence of CO in icy grain mantles. Upon irradiation in its pure ice form, this highly stable species presents a limited ion and photon-induced chemistry, and an efficient non-thermal desorption. Using infrared spectroscopy, single laser interference, and quadrupole mass spectrometry during CO ice deposition, the CO ice density was estimated as a function of deposition temperature. Only minor variations in the density were found. The proposed methodology can be used to obtain the density of other ice components at various deposition temperatures provided that this value of the density is known for one of these temperatures, which is typically the temperature corresponding to the crystalline form. The apparent tendency of the CO ice density to decrease at deposition temperatures below 14 K is in line with recently published colorimetric measurements. This work allowed to revisit the value of the infrared band strength needed for calculation of the CO ice column density in infrared observations, $8.7 \times 10^{-18} ~ {\rm cm ~ molecule}^{-1}$ at 20 K deposition temperature.

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