论文标题
在强耦合条件下，集体光学响应的解离速度放缓
Dissociation slowdown by collective optical response under strong coupling conditions
论文作者
论文摘要
我们认为在正常入射率强的耦合条件下，在强耦合条件下共同耦合的双原子分子合奏。通过直接数值整合，与分子RO振动的自由度明确考虑了光电分离动力学。结果表明，当系统以极化频率驱动时，解离会显着影响（减速）。观察到的效果被证明具有瞬态性质，没有经典的类似物。提出了对极化频率下解离的放缓的直观解释。
We consider an ensemble of diatomic molecules resonantly coupled to an optical cavity under strong coupling conditions at normal incidence. Photodissociation dynamics is examined via direct numerical integration of the coupled Maxwell-Schrodinger equations with molecular ro-vibrational degrees of freedom explicitly taken into account. It is shown that the dissociation is significantly affected (slowed down) when the system is driven at its polaritonic frequencies. The observed effect is demonstrated to be of transient nature and has no classical analog. An intuitive explanation of the dissociation slowdown at polaritonic frequencies is proposed.
