论文标题

四键的定义

Definition of the Tetrel Bond

论文作者

Varadwaj, Pradeep R., Varadwaj, Arpita, Marques, Helder M., Yamashita, Koichi

论文摘要

本文根据当前文献中记录的证据提出了“ Tetrel Bond”一词的定义。它列出了在晶体相中通常观察到的供体,受体以及tetrel键的相关特征和/或从固态和气相中的第一原理计算中出现的。这些可用于识别,炭化和分类,分类和分类分子内和分子内相互作用的独特子集由元素周期表的第14组元素形成,这些元素具有分子实体中具有亲电位点的元素。

This paper proposes a definition of the term "tetrel bond" based on the evidence documented in the current literature. It lists the donors, acceptors, as well as related characteristic features of tetrel bonds that are commonly observed in the crystalline phase and/or that emerge from first principles calculations in the solid-state and gas phases. These may be used to identify, char-acterize and classify the unique subset of inter- and intramolecular interactions formed by the elements of Group 14 of the Periodic Table that possess an electrophilic site in a molecular entity.

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