论文标题
带有手性晶体结构的新的基于GD的磁性复合GDPT $ _2 $ b
New Gd-based magnetic compound GdPt$_2$B with a chiral crystal structure
论文作者
论文摘要
本文中,我们报告了具有手性晶体结构的新型基于GD的磁性化合物GDPT $ _2 $ b。 X射线衍射和化学成分分析显示,GDPT $ _2 $ b。此外,我们使用Czochralski方法成功地生长了GDPT $ _2 $ B的单晶。磁化测量值和Curie $ - $ WEISS分析表明,铁磁相互作用在GDPT $ _2 $ b中占主导地位。在$ t _ {\ rm o} $ = 87 K处的电阻率,磁化率和比热的温度依赖性中观察到了明显的过渡。GDPT$ _2 $ B的磁相图由现场偏振的铁磁区域组成,并具有磁性有序的区域和一个已知的Cherimal helimagagnets的磁性区域。此外,磁化率测量结果揭示了垂直于螺钉轴的磁场中磁性有序相位的自旋重新定向。结果表明,GDPT $ _2 $ b是调查基于稀疏的手性化合物中铁磁和反对称交换相互作用的竞争效果的合适平台。
Herein, we report the discovery of a novel Gd-based magnetic compound GdPt$_2$B with a chiral crystal structure. X-ray diffraction and chemical composition analyses reveal a CePt$_2$B-type crystal structure (space group: $P6_422$) for GdPt$_2$B. Moreover, we successfully grew single crystals of GdPt$_2$B using the Czochralski method. Magnetization measurements and the Curie$-$Weiss analysis demonstrate that the ferromagnetic interaction is dominant in GdPt$_2$B. A clear transition is observed in the temperature dependence of electrical resistivity, magnetic susceptibility, and specific heat at $T_{\rm O}$ = 87 K. The magnetic phase diagram of GdPt$_2$B, which consists of a field-polarized ferromagnetic region and a magnetically ordered region, resembles those of known chiral helimagnets. Furthermore, magnetic susceptibility measurements reveal a possible spin reorientation within the magnetically ordered phase in magnetic fields perpendicular to the screw axis. The results demonstrate that GdPt$_2$B is a suitable platform for investigating the competing effects of ferromagnetic and antisymmetric exchange interactions in rare-earth-based chiral compounds.