论文标题
纠缠群众行动法的神秘化
Demystification of Entangled Mass Action Law
论文作者
论文摘要
最近，Gorban（2021）分析了过渡状态理论的一些动力学悖论，并提出了其修订，该修订赋予了“纠缠的大规模作用法”，其中将产生新的反应作为所考虑的反应机制的补充。这些悖论由于假设反应物和过渡态之间的准quasiequilibrium而产生。在本文中，我们简要介绍了该理论，证明了如何在标准准准稳态近似近似框架中得出纠缠的群众行动法方程，并与辅助反应网络的准广义质量作用定律结合使用，包括反应物和中间体。我们还证明了这些新方程的基本物理属性（积极性），这在原始方法中并不明显。
Recently, Gorban (2021) analysed some kinetic paradoxes of the transition state theory and proposed its revision that gave the "entangled mass action law", in which new reactions were generated as an addition to the reaction mechanism under consideration. These paradoxes arose due to the assumption of quasiequilibrium between reactants and transition states. In this paper, we provided a brief introduction to this theory, demonstrating how the entangled mass action law equations can be derived in the framework of the standard quasi steady state approximation in combination with the quasiequilibrium generalized mass action law for an auxiliary reaction network including reactants and intermediates. We also proved the basic physical property (positivity) for these new equations, which was not obvious in the original approach.
