论文标题

切向驱动的活动极性线性聚合物 - 一项分析研究

Tangentially Driven Active Polar Linear Polymers -- An Analytical Study

论文作者

Philipps, Christian A., Gompper, Gerhard, Winkler, Roland G.

论文摘要

分析研究了分离的柔性活性极性线性聚合物(APLP)的构象和动力学特性。 APLP的建模为以离散和连续表示的切向活性力增强的高斯珠弹簧线性链。极力导致线性非铁运动运动方程,该方程是通过征函数膨胀来解决的。我们的计算表明,聚合物构象与活性无关。相反,切向推进强烈影响聚合物动力学,并产生活跃的弹道制度以及活性增强的长期扩散,在被动系统中都不存在。极力意味着特征功能表示中模式的耦合,特别是与翻译模式的耦合,对聚合物动力学具有强大的影响。与活动性布朗聚合物相比,比旋转半径小于其旋转半径的总均值位移是由活跃的内部动力学而不是集体质量中心运动确定的,这反映了推进机制的明显差异。

The conformational and dynamical properties of isolated flexible active polar linear polymers (APLPs) are studied analytically. The APLPs are modeled as Gaussian bead-spring linear chains augmented by tangential active forces, both in a discrete and continuous representations. The polar forces lead to linear non-Hermitian equations of motion, which are solved by an eigenfunction expansion in terms of a biorthogonal basis set. Our calculations show that the polymer conformations are independent of activity. On the contrary, tangential propulsion strongly impacts the polymer dynamics and yields an active ballistic regime as well as activity-enhanced long-time diffusion, regimes which are both absent in passive systems. The polar forces imply a coupling of modes in the eigenfunction representation, in particular with the translational mode, with a respective strong influence on the polymer dynamics. The total polymer mean-square displacement on scales smaller than their radius of gyration is determined by the active internal dynamics rather than the collective center-of-mass motion, in contrast to active Brownian polymers, reflecting the distinct difference in the propulsion mechanism.

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