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The treatment of 1 + 3 covariant perturbation in a multifluid cosmology with the consideration of f (G) gravity, G being the Gauss-Bonnet term, is done in the present paper. We define a set of covariant and gauge-invariant variables to describe density, velocity and entropy perturbations for both the total matter and component fluids. We then use different techniques such as scalar decomposition, harmonic decomposition, quasi-static approximation together with the redshift transformation to get simplified perturbation equations for analysis. We then discuss number of interesting applications like the case where the universe is filled with a mixture of radiation and Gauss-Bonnet fluids as well as dust with Gauss-Bonnet fluids for both short- and long-wavelength limits. Considering polynomial f (G) model, we get numerical solutions of energy density perturbations and show that they decay with increase in redshift. This feature shows that under f (G) gravity, specifically under the considered f (G) model, one expects that the formation of the structure in the late Universe is enhanced.