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We present and amplify some of our previous statements on non-canonical interrelations between the solutions to free Dirac equation (DE) and Klein-Gordon equation (KGE). We demonstrate that all the solutions to the DE (possessing point- or string-like singularities) can be obtained via differentiation of a corresponding pair of the KGE solutions for a doublet of scalar fields. On this way we obtain a "spinor analogue" of the mesonic Yukawa potential and previously unknown chains of solutions to DE and KGE, as well as an exceptional solution to the KGE and DE with a finite value of the field charge ("localized" de Broglie wave). The pair of scalar "potentials" is defined up to a gauge transformation under which corresponding solution of the DE remains invariant. Under transformations of Lorentz group, canonical spinor transformations form only a subclass of a more general class of transformations of the solutions to DE upon which the generating scalar potentials undergo transformations of internal symmetry intermixing their components. Under continious turn by one complete revolution the transforming solutions, as a rule, return back to their initial values ("spinor two-valuedness" is absent). With arbitrary solution of the DE one can associate, apart of the standard one, a non-canonical set of conserved quantities, positive definite "energy" density among them, and with any KGE solution -- positive definite "probability density", etc. Finally, we discuss a generalization of the proposed procedure to the case when the external electromagnetic field is present