论文标题
HCl，DCL和TCL双原子分子处于其基态：预测出生的脑旋转光谱
HCl, DCl and TCl diatomic molecules in their ground state: predicting Born-Oppenheimer rovibrational spectra
论文作者
论文摘要
分子状态的分析型（B-O）电势曲线的基态$ x^1σ^+$的分子（H，h，d，t）Cl是为整个核内距离$ r \ in [0，\ infty）$的整个范围而构建的，与RKR潜在的curifore curnive verifient corifience corifore cur的准确性相比，该图的精确度的精度为3-5个图形。在能量中的精度为3-4个重要数字，HCl（DCL，TCL）的836（1625，2366）B-O ROVIBRATICATY BOND BONDEND状态具有最大振动数$ν_{max} = 20 \ 20 \，（29，35）$和最大动量$ l_ $ l_ $ l_ ^ 64，（29，35） （46，63）具有能量$ \ Lessim 10^{ - 4} $ HARTREE的弱结合状态（接近离解限）。指示现有的实验数据不足，并针对所有HCL，DCL，TCL分子进行了大部分缺失的旋转状态的预测。
The analytic Born-Oppenheimer (B-O) potential curve for the ground state $X^1Σ^+$ of the molecule (H,D,T)Cl is constructed for the whole range of internuclear distances $R \in [0,\infty)$ with an accuracy of 3-5 figures in comparison with the RKR-style potential curve derived from available experimental data on vibrational energies. With an accuracy of 3-4 significant figures in the energies, it is predicted for HCl (DCl, TCl) the 836 (1625, 2366) B-O rovibrational bound states with maximal vibrational number $ν_{max} = 20\, (29, 35)$ and maximal angular momentum $L_{max} = 64\, (90, 109)$ including 24 (46, 63) weakly-bound states (close to the dissociation limit) with energies $\lesssim 10^{-4}$ Hartree. Insufficiency of existing experimental data is indicated and a prediction of the bulk of missing rovibrational states is made for all HCl, DCl, TCl molecules.
