论文标题
几乎关键的液滴扩散
Near-critical spreading of droplets
论文作者
论文摘要
我们使用实验,润滑理论和有限元数值模拟的组合研究了液滴在几乎临界相分离的液体混合物中的扩散。当临界温度接近时,可以很好地验证描述粘性液滴扩散的经典制革商定律。此外,该法律中出现的微观截止长度尺度是每个给定温度的单个自由参数。在总润湿条件下,该长度被解释为在表观接触线之前存在的薄前体膜的厚度。不同演变对单个坦纳的主曲线的崩溃表明,在进入波动主导的政权之前,粘性传播的普遍性。最后,我们的结果揭示了在接近临界温度时,前体膜的违反直觉和锐利的变薄,这归因于临界点上消失的扩散参数。
We study the spreading of droplets in a near-critical phase-separated liquid mixture, using a combination of experiments, lubrication theory and finite-element numerical simulations. The classical Tanner's law describing the spreading of viscous droplets is robustly verified when the critical temperature is neared. Furthermore, the microscopic cut-off length scale emerging in this law is obtained as a single free parameter for each given temperature. In total-wetting conditions, this length is interpreted as the thickness of the thin precursor film present ahead of the apparent contact line. The collapse of the different evolutions onto a single Tanner-like master curve demonstrates the universality of viscous spreading before entering in the fluctuation-dominated regime. Finally, our results reveal a counter-intuitive and sharp thinning of the precursor film when approaching the critical temperature, which is attributed to the vanishing spreading parameter at the critical point.