论文标题
通过表面电化学控制的Hafnia中的铁电性
Ferroelectricity in Hafnia Controlled via Surface Electrochemical State
论文作者
论文摘要
包括高度非常规的物理机制以及将这些材料整合到半导体工作流中,包括Hafnia和氧化菌在内的二元氧化物中的铁电性引起了科学界的注意。在过去的十年中,有人认为,唤醒现象和对电极和加工条件的极端敏感性表明,这些材料中的铁电性与其他机制紧密相结合,以及包括离子子系统或应变在内的可能的候选者。在这里,我们认为,由于铁电和结构不稳定性之间的大量竞争,这些材料的性质出现了,类似于经典的抗fiferroelectrics,以及由状态在表面和内部接口处的状态密度有限密度介导的非局部筛选。通过通过环境和超高真空PFM实现的电化学和静电控制的解耦,我们表明这些材料表明了丰富的铁族行为谱,包括部分压力和温度诱导的FE和AFE行为之间的过渡。这些行为与抗体电离模型一致,并提出了基于HAFNIA的设备优化的新型策略。
Ferroelectricity in binary oxides including hafnia and zirconia have riveted the attention of the scientific community due to highly unconventional physical mechanisms and the potential for integration of these materials into semiconductor workflows. Over the last decade, it has been argued that behaviors such as wake-up phenomena and an extreme sensitivity to electrode and processing conditions suggests that ferroelectricity in these materials is strongly coupled with additional mechanisms, with possible candidates including the ionic subsystem or strain. Here we argue that the properties of these materials emerge due to the interplay between the bulk competition between ferroelectric and structural instabilities, similar to that in classical antiferroelectrics, coupled with non-local screening mediated by the finite density of states at surfaces and internal interfaces. Via decoupling of electrochemical and electrostatic controls realized via environmental and ultra-high vacuum PFM, we show that these materials demonstrate a rich spectrum of ferroic behaviors including partial pressure- and temperature-induced transitions between FE and AFE behaviors. These behaviors are consistent with an antiferroionic model and suggest novel strategies for hafnia-based device optimization.