论文标题
在地下压力和温度条件下砂岩中氢存储的孔尺度可视化:捕获,溶解和润湿性
Pore-Scale Visualization of Hydrogen Storage in a Sandstone at Subsurface Pressure and Temperature Conditions: Trapping, Dissolution and Wettability
论文作者
论文摘要
全球实现净零的承诺导致对绿色氢的生产和使用的投资增加(H2)。但是,满足未来需求所需的大量数量将需要新的存储设施。 H2的地下存储是一种潜在的可行解决方案,但由于H2的独特物理和化学特性,尚未在地下环境中进行数量研究,因此提出了独特的挑战。我们已经进行了原位X射线流实验,以研究H2注射期间孔隙尺度流体位移过程的基本原理,以最初的盐水饱和底栖动物砂岩样品。遵循了两种不同的注射方案,在温度和压力条件下,H2平衡的盐水和非H2平衡的盐水的位移代表了深地下储层。两个位移循环后,发现H2分别为53.72和52.72,在两个位移循环后不润湿盐水。我们还发现,与H2平衡的盐水(31.6%)相比,非H2平衡的盐水的H2回收率更高(43.1%)(31.6%),表明在储层条件下,H2在未平衡的盐水中的潜在溶解。我们的结果表明,H2存储确实可能是能量存储的合适策略,但是需要进行大量研究来充分理解储层条件下的孔隙规模相互作用。
The global commitment to achieve net-zero has led to increasing investment towards the production and usage of green hydrogen (H2).However, the massive quantity needed to match future demand will require new storage facilities. Underground storage of H2 is a potentially viable solution, but poses unique challenges due to the distinctive physical and chemical properties of H2, that have yet to be studied quantitatively in the subsurface environment. We have performed in situ X-ray flow experiments to investigate the fundamentals of pore-scale fluid displacement processes during H2 injection into an initially brine saturated Bentheimer sandstone sample. Two different injection schemes were followed, the displacement of H2 with H2-equilibrated brine and non-H2-equilibrated brine both at temperature and pressure conditions representative of deep underground reservoirs. H2 was found to be non-wetting to brine after both displacement cycles, with average contact angles between 53.72 and 52.72, respectively. We also found a higher recovery of H2 (43.1%) for non-H2-equilibrated brine compared to that of H2-equilibrated brine (31.6%), indicating potential dissolution of H2 in unequilibrated brine at reservoir conditions. Our results suggest that H2 storage may indeed be a suitable strategy for energy storage, but considerable further research is needed to fully comprehend the pore-scale interactions at reservoir conditions.