论文标题

Caf $ _2 $中的伪脱菜的Zeeman-hyperfine测量值:ho $^{3+} $

Zeeman-Hyperfine Measurements of a Pseudo-Degenerate Quadruplet in CaF$_2$:Ho$^{3+}$

论文作者

Smith, Kieran M., Reid, Michael F., Wells, Jon-Paul R.

论文摘要

我们报告了Zeeman Infra-Red光谱$^5 $^5 $ i $ _8 \ rightarrow^5 $ i $ i $ _7 $ ho $^{3+} $的过渡c $ _ {\ rm 4v} $(f $^ - $)中心的Caf $ _2 $ _2 $ _2 $ \ $ \ $ \ lang lang lang lang lang lang lang lang lang lang lang。过渡到最低的$^5 $ i $ _7 $状态,一个孤立的电子双线,以及下一组州,一个伪Quadrulet,由Doublet和两个附近的Singlet组成,表现出强烈的非线性Zeeman Splittings和强度变化。基于晶体场分析的模拟光谱给出了与数据的出色近似,这说明了参数化晶体场方法的强烈预测能力。还可以预测超精细分裂中的抗跨跨跨分裂的基础,这是稀土掺杂绝缘电介质中的量子信息存储的基础。

We report Zeeman infra-red spectroscopy of electronic-nuclear levels of $^5$I$_8 \rightarrow ^5$I$_7$ transitions of Ho$^{3+}$ in the C$_{\rm 4v}$(F$^-$) centre in CaF$_2$ with the magnetic field along the $\langle 111\rangle$ direction of the crystal. Transitions to the lowest $^5$I$_7$ state, an isolated electronic doublet, and the next group of states, a pseudo-quadruplet consisting of a doublet and two nearby singlets, exhibit strongly non-linear Zeeman splittings and intensity variations. Simulated spectra based upon a crystal-field analysis give an excellent approximation to the data, illustrating the strong predictive ability of the parametrised crystal-field approach. Anti-crossings in the hyperfine splittings, the basis of quantum information storage in rare-earth doped insulating dielectrics, are also predicted.

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