论文标题
超龙石墨烯纳米纤维在绝缘底物上的催化生长
Catalytic growth of ultralong graphene nanoribbons on insulating substrates
论文作者
论文摘要
具有少数纳米宽度的石墨烯纳米纤维(GNR)是有希望的未来纳米电动应用的候选者,因为它们的结构可调式带盖,超高载流子迁移率和出色的稳定性。但是,微米长的GNR在绝缘底物上的直接生长对于制造纳米电子设备至关重要,这是巨大的挑战。在这里,我们报告了通过纳米粒子催化的化学蒸气沉积(CVD)的绝缘六角硼(H-BN)底物的外延生长。合成长度高达10μm的超鼻中GNR。值得注意的是,生长的GNR在晶体学上与H-BN底物对齐,形成一维(1D)Moiré超晶格。扫描隧道显微镜显示,对于在传导石墨底物上生长的类似GNR,平均宽度为2 nm,典型的带隙为〜1 eV。完全原子的计算模拟支持实验结果,并揭示了成核阶段中GNR和碳纳米管(CNT)形成之间的竞争,并且在整个生长阶段,GNRS在H-BN底物上滑动了GNR。我们的研究提供了一种可扩展的单步方法,用于在绝缘底物上生长微米长的狭窄GNR,从而为探索高质量GNR设备的性能和1DMoiré超级晶格的基本物理学开辟了途径。
Graphene nanoribbons (GNRs) with widths of a few nanometres are promising candidates for future nano-electronic applications due to their structurally tunable bandgaps, ultrahigh carrier mobilities, and exceptional stability. However, the direct growth of micrometre-long GNRs on insulating substrates, which is essential for the fabrication of nano-electronic devices, remains an immense challenge. Here, we report the epitaxial growth of GNRs on an insulating hexagonal boron nitride (h-BN) substrate through nanoparticle-catalysed chemical vapor deposition (CVD). Ultra-narrow GNRs with lengths of up to 10 μm are synthesized. Remarkably, the as-grown GNRs are crystallographically aligned with the h-BN substrate, forming one-dimensional (1D) moiré superlattices. Scanning tunnelling microscopy reveals an average width of 2 nm and a typical bandgap of ~1 eV for similar GNRs grown on conducting graphite substrates. Fully atomistic computational simulations support the experimental results and reveal a competition between the formation of GNRs and carbon nanotubes (CNTs) during the nucleation stage, and van der Waals sliding of the GNRs on the h-BN substrate throughout the growth stage. Our study provides a scalable, single-step method for growing micrometre-long narrow GNRs on insulating substrates, thus opening a route to explore the performance of high-quality GNR devices and the fundamental physics of 1D moiré superlattices.