论文标题

无PB(1-X)BA(ZR0.2TI0.8)O3-X(BA0.7CA0.3)TIO3 Ceramics中局部结构异质性和远距离铁电性的共存

Coexistence of local structural heterogeneities and long-range ferroelectricity in Pb-free (1-x)Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3 ceramics

论文作者

Dey, Koushik, Ahad, Abdul, Gautam, Kamini, Tripathy, Abinash, Majid, Sofi Suhail, Francoual, Sonia, Richter, Carsten, Singh, MN, Sagdeo, Archna, Welter, Edmund, Vittayakorn, Naratip, Sathe, Vasant G., Rawat, Rajeev, Shukla, Dinesh Kumar

论文摘要

环境良性(1-x)ba(ti $ _ {0.8} $ zr $ _ {0.2} $)o $ $ _3 $ -x(ba $ _ {0.7} $ ca $ _ {0.3} $ _ {0.3} $)莱特牧师。 \ textbf {103},257602(2009)]。在这封信中,通过关注局部和平均结构与宏观机电和介电测量相结合,我们证明了四方BZT-BCT陶瓷中的结构性质关系。在高温立方至四方相变的过程中,在低于$ \ sim $ 477 k的温度下,通过自发体积的铁电驱动器来表现出极性纳米区域。八面体。这些八面体在两极分化过程中损害了他们的个性。通过压电响应力显微镜观察到嵌入在T $ _ {M} $以下的宏观铁电区域内的域域的存在以及它们的分层排列。当比较polded和未固定样品的极性化时,也观察到结构/极性异质性的存在的效果。发现固定样品更容易受到电场的影响。此外,通过使用依赖电场的X射线衍射研究,我们还表明,该磁场下的陶瓷显示了四方变形的减少,这与较早的报告一致。

Environmentally benign (1-x)Ba(Ti$_{0.8}$Zr$_{0.2}$)O$_3$-x(Ba$_{0.7}$Ca$_{0.3}$)TiO$_3$ (BZT-BCT) ceramics are promising materials due to their remarkable high piezoresponse [Liu and Ren, Phys. Rev. Lett. \textbf{103}, 257602 (2009)]. In this Letter, by focusing on local and average structure in combination with macroscopic electromechanical and dielectric measurements we demonstrate the structure property relationship in the tetragonal BZT-BCT ceramic. During high-temperature cubic to tetragonal phase transformation, polar nanoregions are manifested through the spontaneous volume ferroelectrostriction at temperatures below $\sim$ 477 K. Temperature-dependent local structural investigations across the Zr K edge extended x-ray absorption fine structure spectroscopy reveal an anomalous collaboration between the ZrO$_{6}$ and TiO$_6$ octahedra. These octahedra compromise their individuality during polarization development. The presence of domains of submicron size embedded inside the macroscopic ferroelectric regions below T$_{m}$, as well as their hierarchical arrangement, is observed by piezo-response force microscopy. Effects of the existence of the structural/polar heterogeneities below T$_{m}$ are observed also when polarizibilities of the poled and the unpoled samples are compared; the poled sample is found to be more susceptible to the electric field. In addition, by using electric field dependent x-ray diffraction studies we also show that this ceramic under field exhibits reduction of tetragonal distortion, which is consistent with earlier reports.

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