论文标题

磁相共存对多晶SM0.5Y0.5FE0.5FE0.58MN0.42O3中自旋 - 音波耦合和磁电效应的影响

Effect of magnetic phase coexistence on spin-phonon coupling and magnetoelectric effect in polycrystalline Sm0.5Y0.5Fe0.58Mn0.42O3

论文作者

Raut, S., Chakravarty, S., Mohanty, H. S, Mahapatra, S., Bhardwaj, S., Awasthi, A. M., Kar, B., Singh, K., Chandra, M., Lakhani, A., Ganesan, V., Patidar, M. Mishra, Sharma, R. K., Srihari, Velaga, Poswal, H. K., Mukherjee, S., Giri, S., Panigrahi, S

论文摘要

SM0.5Y0.5FE0.58MN0.42O3的多晶共掺杂样品是通过固态反应途径制备的,并且已经研究了其与其相关性的各种物理特性。在样品上的DC磁化测量表明,Tn = 361 K处的铁磁(WFM)过渡较弱,其后是TSR1 = 348 K处的不完整的自旋重新定位(SR)过渡。 260 K.该化合物在100 OE的低测量场时表现出低于补偿温度(TCOMP)= 92 K的磁化逆转。在低于71 K的进一步低温下,该化合物还表现出零场冷却的记忆效应,证实了重新进入的Spinglass状态形成。稳健的磁性(MD)磁电耦合已通过依赖性的介电和电阻率测量在当前材料中建立。在TFE = 108 K以下的样品中发现了具有相当大的饱和极化值(= 0.06微C/CM2)的真实铁电过渡。我们观察到,来自温度依赖性的Raman光谱型,跨TSR和TN的强烈自旋 - 音波偶联(SPC)负责对内在的MAGNETOSIC效果负责。该SPC还稳定了材料中TFE以下的铁电状态。晶格(声子)的微妙相互作用,电荷和旋转控制了材料所研究的物理特性中观察到的特征,使样品成为有希望的多功能材料。

The polycrystalline co-doped samples of Sm0.5Y0.5Fe0.58Mn0.42O3 were prepared by solid-state reaction route and its various physical properties with their correlations have been investigated. The dc magnetization measurements on the sample revealed a weak ferromagnetic (WFM) transition at TN=361 K that is followed by an incomplete spin reorientation (SR) transition at TSR1= 348 K. A first order magnetic transition (FOMT) around 292 K completes the spin reorientation transition and the material enters into a nearly collinear antiferromagnetic (AFM) state for T < 260 K. The compound exhibited magnetization reversal below the compensation temperature (Tcomp) = 92 K at low measured field of 100 Oe. At further low temperature below 71 K, the compound also exhibited Zero-field cooled memory effects confirming a reentrant spinglass state formation. Robust magnetodielectric (MD) magnetoelectric coupling has been established in the present material through field dependent dielectric and resistivity measurements. True ferroelectric transition with a considerable value of saturation polarization (= 0.06 micro C/cm2 at 15 K) have been found in the specimen below TFE= 108 K. We observed an intense spin-phonon coupling (SPC) across TSR and TN from the temperature dependent Raman spectroscopy and is responsible for the intrinsic magnetoelectric effect. This SPC also stabilizes the ferroelectric state below TFE in the material. The delicate interplay of the lattice (Phonons), charge and spins governs the observed features in the investigated physical properties of the material that makes the specimen a promising multifunctional material.

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