论文标题
热力学是基本的吗?
Is thermodynamics fundamental?
论文作者
论文摘要
在物理哲学中,热力学是一种非基础理论。这是一个尤其是通过认为可以简化为另一种统计力学的理论的范式示例的事实。例如,尽管该陈述对于各种系统不正确,但“温度是平均分子动能”的陈述已成为成功减少的教科书示例。在本文中,我们捍卫了热力学是一种基本理论,我们根据最近的物理研究的四个案例研究来证明这一立场是合理的。我们解释了熵重力(1)和黑洞热力学(2)如何作为案例研究,以阻止热力学的降低。此外,我们讨论了相变的降低性问题,并认为分叉理论(3)即使在有限的系统中也可以在热力学水平上对“相变”进行建模。还表明,尽管最近提出相反的说法,但在莫里兹万齐格形式上的不可逆传输方程(4)并没有构成量子力学的热力学减少。最后,我们简要讨论了一些不基于减少的热力学的基础性的论点。
It is a common view in philosophy of physics that thermodynamics is a non-fundamental theory. This is motivated in particular by the fact that thermodynamics is considered to be a paradigmatic example for a theory that can be reduced to another one, namely statistical mechanics. For instance, the statement "temperature is mean molecular kinetic energy" has become a textbook example for a successful reduction, despite the fact that this statement is not correct for a large variety of systems. In this article, we defend the view that thermodynamics is a fundamental theory, a position that we justify based on four case studies from recent physical research. We explain how entropic gravity (1) and black hole thermodynamics (2) can serve as case studies for the multiple realizability problem which blocks the reduction of thermodynamics. Moreover, we discuss the problem of the reducibility of phase transitions and argue that bifurcation theory (3) allows the modelling of "phase transitions" on a thermodynamic level even in finite systems. It is also shown that the derivation of irreversible transport equations in the Mori-Zwanzig formalism (4) does not, despite recent claims to the contrary, constitute a reduction of thermodynamics to quantum mechanics. Finally, we briefly discuss some arguments against the fundamentality of thermodynamics that are not based on reduction.