论文标题
角度分辨的极化拉曼光谱法，以区分I期石墨插入化合物与thrium，铀和p的化合物
Angle-resolved polarized Raman spectroscopy for distinguishing stage-I graphite intercalation compounds with Thorium, Uranium and Plutonium
论文作者
论文摘要
石墨插入化合物（GICS）具有几何各向异性和强型电子耦合的偶然性，并且已经如火如荼地展示了它们在纳米电视中应用的巨大潜力。我选择了具有价电子排列的Actinide组的代表性三个元素：Thorium（th）（[RN] 6D27S2），铀（U）（[RN] 5F36D17S2），plutonium（pu）（PU）（[RN] 5F67S2）。我计算了他们的声子光谱，并证明了通过角度分辨极化拉曼光谱法对actinide石墨插入化合物的原子级微结构鉴定。
Graphite intercalation compounds (GICs) with the geometrical anisotropy and strong electron-phonon coupling are in full swing and have shown their great potential for applications in nanodevices. I selected representative three elements in actinide group with valence electron arrangement: Thorium (Th) ([Rn]6d27s2), Uranium (U) ([Rn]5f36d17s2), Plutonium (Pu) ([Rn]5f67s2). I calculated their phonon spectra and demonstrated the atomic-scale microstructure identification of actinide graphite intercalation compounds by angle-resolved polarized Raman spectroscopy.
