论文标题

审查的基于物理锂离子电池模型的连续体

A Continuum of Physics-Based Lithium-Ion Battery Models Reviewed

论文作者

Planella, Ferran Brosa, Ai, Weilong, Boyce, Adam M., Ghosh, Abir, Korotkin, Ivan, Sahu, Smita, Sulzer, Valentin, Timms, Robert, Tranter, Thomas G., Zyskin, Maxim, Cooper, Samuel J., Edge, Jacqueline S., Foster, Jamie M., Marinescu, Monica, Wu, Billy, Richardson, Giles

论文摘要

从多孔电极理论得出的基于物理学的电化学电池模型是理解锂离子电池以及改善其设计和管理的非常强大的工具。不同应用需要不同的模型保真度,因此需要模型的复杂性。例如,在电池设计中,我们可以提供更长的计算时间和功能强大的计算机的使用,而对于实时电池控制(例如,在电动汽车中),我们需要使用简单的设备执行非常快速的计算。因此,广泛使用了以较低的计算成本保留大多数功能的简化模型。即使在文献中,我们经常发现这些简化的模型独立提出,从而导致模型之间的不一致,但实际上可以使用统一和系统的框架从更复杂的模型中得出它们。在这篇综述中,我们展示了从高保真微观模型开始,并将其一直降低到单个粒子模型(SPM),在此过程中得出其他常见模型,例如Doyle-Fuller-Newman(DFN)模型。我们还提供了有关每个模型的优点和缺点的批判性讨论,这可以帮助特定应用程序的模型选择。最后,我们提供了模型可能扩展的概述,并特别关注热模型。这些扩展中的任何一个都可以纳入微观模型,并重新应用还原的还原框架,以导致新一代简化的多物理模型。

Physics-based electrochemical battery models derived from porous electrode theory are a very powerful tool for understanding lithium-ion batteries, as well as for improving their design and management. Different model fidelity, and thus model complexity, is needed for different applications. For example, in battery design we can afford longer computational times and the use of powerful computers, while for real-time battery control (e.g. in electric vehicles) we need to perform very fast calculations using simple devices. For this reason, simplified models that retain most of the features at a lower computational cost are widely used. Even though in the literature we often find these simplified models posed independently, leading to inconsistencies between models, they can actually be derived from more complicated models using a unified and systematic framework. In this review, we showcase this reductive framework, starting from a high-fidelity microscale model and reducing it all the way down to the Single Particle Model (SPM), deriving in the process other common models, such as the Doyle-Fuller-Newman (DFN) model. We also provide a critical discussion on the advantages and shortcomings of each of the models, which can aid model selection for a particular application. Finally, we provide an overview of possible extensions to the models, with a special focus on thermal models. Any of these extensions could be incorporated into the microscale model and the reductive framework re-applied to lead to a new generation of simplified, multi-physics models.

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