论文标题
水中田间引起的电子产生：溶解动力学和多体相互作用
Field-Induced Electron Generation in Water: Solvation Dynamics and Many-Body Interactions
论文作者
论文摘要
溶剂化的电子代表液体环境中的基本量子系统。在水中溶剂化的电子因其典型特性，其在辐射化学中的作用以及其与电荷分离和运输的相关性，引起了人们的浓厚兴趣。在超快时间尺度上发生了水中光生电子的非平衡动力学，包括电荷转移，定位和耗能过程。我们对在存在外部Terahertz场的存在下产生电子的波动电场的作用提出了新的见解，并介绍了溶剂化电子的二极化多体性能。本文将对实验和理论结果的最新结果与对水中电子的基本电相互作用的讨论结合了起来。
The solvated electron represents an elementary quantum system in a liquid environment. Electrons solvated in water have raised strong interest because of their prototypical properties, their role in radiation chemistry, and their relevance for charge separation and transport. Nonequilibrium dynamics of photogenerated electrons in water occur on ultrafast time scales and include charge transfer, localization, and energy dissipation processes. We present new insight in the role of fluctuating electric fields of the liquid for generating electrons in presence of an external terahertz field and address polaronic many-body properties of solvated electrons. The article combines a review of recent results from experiment and theory with a discussion of basic electric interactions of electrons in water.
