论文标题
电子诱导的激发,重新组合和分离分子离子,启动复杂有机分子的形成
Electron-induced excitation, recombination and dissociation of molecular ions initiating the formation of complex organic molecules
论文作者
论文摘要
我们回顾了diATOMIC和小多原子分子离子的解离性重组和RO振动激发的研究。特别是,我们展示了如何使用多通道量子缺陷理论(MQDT)和R-Matrix方法来计算阳离子的阳离子和速率系数,该阳离子在良好定义的地面电子状态的RO振动水平(从sub-m-Mev最多少量EV碰撞能量)中。 将最新的MQDT结果与其他理论数据或在存储环实验中获得的测量数据进行了比较。
We review the study of dissociative recombination and ro-vibrational excitation of diatomic and small polyatomic molecular ions initiating complex organic molecules formation. In particular, we show how Multichannel Quantum Defect Theory (MQDT) and R-matrix methods are used to compute cross sections and rate coefficients for cations in well defined ro-vibrational levels of the ground electronic state, from sub-meV up to few eV collision energies. The most recent MQDT results are compared with either other theoretical data, or with measured data obtained in storage-ring experiments.