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A critical problem in the financial world deals with the management of risk, from regulatory risk to portfolio risk. Many such problems involve the analysis of securities modelled by complex dynamics that cannot be captured analytically, and hence rely on numerical techniques that simulate the stochastic nature of the underlying variables. These techniques may be computationally difficult or demanding. Hence, improving these methods offers a variety of opportunities for quantum algorithms. In this work, we study the problem of Credit Valuation Adjustments (CVAs) which has significant importance in the valuation of derivative portfolios. As a variant, we also consider the problem of pricing a portfolio of many different financial options. We propose quantum algorithms that accelerate statistical sampling processes to approximate the price of the multi-option portfolio and the CVA under different measures of dispersion. Technically, our algorithms are based on enhancing the quantum Monte Carlo (QMC) algorithms by Montanaro with an unbiased version of quantum amplitude estimation. We analyse the conditions under which we may employ these techniques and demonstrate the application of QMC techniques on CVA approximation when particular bounds for the variance of CVA are known.