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The first aim of this paper is to introduce a class of Markov chains on $\mathbb{Z}_+$ which are discrete self-similar in the sense that their semigroups satisfy an invariance property expressed in terms of a discrete random dilation operator. After showing that this latter property requires the chains to be upward skip-free, we first establish a gateway relation, a concept introduced in [26], between the semigroup of such chains and the one of spectrally negative self-similar Markov processes on $\mathbb{R}_+$. As a by-product, we prove that each of these Markov chains, after an appropriate scaling, converge in the Skorohod metric, to the associated self-similar Markov process. By a linear perturbation of the generator of these Markov chains, we obtain a class of ergodic Markov chains, which are non-reversible. By means of intertwining and interweaving relations, where the latter was recently introduced in [27], we derive several deep analytical properties of such ergodic chains including the description of the spectrum, the spectral expansion of their semigroups, the study of their convergence to equilibrium in the $Φ$-entropy sense as well as their hypercontractivity property.