论文标题

量子信息在分子中争夺

Quantum Information Scrambling in Molecules

论文作者

Zhang, Chenghao, Wolynes, Peter G., Gruebele, Martin

论文摘要

当更改动力学的初始条件时,量子系统范围内量子系统的速度速度可用于探测量阶的相关器(OTOC)。在足够大的量子系统中,可以从OTOC中提取Lyapunov系数的量子类似物,该量子类似物描述了经典混沌系统被炒作的时间尺度。 OTOC仅应用于非常有限的玩具模型,例如与黑洞信息相关的SYK模型,但它们可以在量子系统中找到更广泛的适用性,以便在量子系统中与实验进行比较。已知多原子分子的振动会从低能处的常规动力学转变为足够高的能量流动。因此,分子代表理想的量子系统,用于研究中等大小的多体系统(这里的自由度6至36度)。通过计算量子耳端及其经典对应物,我们可以量化信息在分子系统中机械地“扰列”量子的方式。在探索状态的全密度时,在早期的“弹道”动力学和OTOC的晚期“饱和”之间,确实存在一个量子lyapunov系数,可以为所有分子定义本研究中的所有分子。与实验速率数据的比较表明,通过OTOC测量的缓慢争夺可以达到分子反应动力学的时间尺度。即使对于我们讨论的最小分子,MALDACENA的结合仍然可以通过正则化的OTOC来满足,但没有通过未注册的OTOC来满足,这强调了前者对于讨论在这种类型的中等尺寸量子系统中争吵的信息更有用。

Out-of-time-order correlators (OTOCs) can be used to probe how quickly a quantum system scrambles information when the initial conditions of the dynamics are changed. In sufficiently large quantum systems, one can extract from the OTOC the quantum analog of the Lyapunov coefficient that describes the time scale on which a classical chaotic system becomes scrambled. OTOCs have been applied only to a very limited number of toy models, such as the SYK model connected with black hole information scrambling, but they could find much wider applicability for information scrambling in quantum systems that allow comparison with experiments. The vibrations of polyatomic molecules are known to undergo a transition from regular dynamics at low energy to facile energy flow at sufficiently high energy. Molecules therefore represent ideal quantum systems to study scrambling in many-body systems of moderate size (here 6 to 36 degrees of freedom). By computing quantum OTOCs and their classical counterparts we quantify how information becomes 'scrambled' quantum mechanically in molecular systems. Between early 'ballistic' dynamics, and late 'saturation' of the OTOC when the full density of states is explored, there is indeed a regime where a quantum Lyapunov coefficient can be defined for all molecules in this study. Comparison with experimental rate data shows that slow scrambling as measured by the OTOC can reach the time scale of molecular reaction dynamics. Even for the smallest molecules we discuss, the Maldacena bound remains satisfied by regularized OTOCs, but not by unregularized OTOCs, highlighting that the former are more useful for discussing information scrambling in this type of moderate-size quantum system.

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