论文标题
Bjerrum对对带电表面靠近电解质溶液中静电性能的影响:平均场接近
Effect of Bjerrum pairs on electrostatic properties in an electrolyte solution near charged surfaces: A mean-field approach
论文作者
论文摘要
在本文中,我们研究了离子关联的后果,再加上有限尺寸效应和Bjerrum Pairs以及离子和水分子的定向顺序的考虑,在带电表面附近的电动双层上。基于晶格统计力学,考虑了离子,bjerrum对和溶剂分子的有限尺寸和偶极矩,我们考虑了Bjerrum Pairs的形成,并得出了Bjerrum Pair Pair Mument的数学表达式,以及阳离子/阴离子的密度和水分子数量密度。 我们揭示了几种重要现象。首先,结果表明,我们的方法自然产生了平衡常数,以实现Bjerrum对和离子之间的离解相关平衡。其次,在低表面电荷密度下,Bjerrum对的整体浓度增加会增强介电常数并降低差异电容。接下来,对于酒精电解质溶液中的Bjerrum对具有很高的偶极矩值,Bjerrum对数密度随着距带电表面的距离的降低而增加,并且与Bjerrum-Pair-Pair-Pair-Pole偶极矩值较低的情况相比,差异电容和PLASTINATION较高。最后,我们表明,bjerrum对的浓度和偶极矩的差异会导致两个类似带电的表面之间的渗透压变化。
In this paper, we investigate the consequences of ion association, coupled with the considerations of finite size effects and orientational ordering of Bjerrum pairs as well as ions and water molecules, on electric double layer near charged surfaces. Based on the lattice statistical mechanics accounting for finite sizes and dipole moments of ions, Bjerrum pairs and solvent molecules, we consider the formation of Bjerrum pairs and derive the mathematical expressions for Bjerrum pair number density as well as cation/anion number density and water molecule number density. We reveal the several significant phenomena. Firstly, it is shown that our approach naturally yields the equilibrium constant for dissociation-association equilibrium between Bjerrum pairs and ions. Secondly, at low surface charge densities, an increase in the bulk concentration of Bjerrum pairs enhances the permittivity and decreases the differential capacitance. Next, for cases where Bjerrum pairs in an alcohol electrolyte solution have a high value of dipole moment, Bjerrum pair number density increases with decreasing distance from the charged surface, and differential capacitance and permittivity is high compared to ones for the cases with lower values of Bjerrum-pair dipole moments. Finally, we show that the difference in concentration and dipole moment of Bjerrum pairs can lead to some variation in osmotic pressure between two similarly charged surfaces.