论文标题
被动膜的生长：Ti和类似金属的证据
The Growth of Passive Membranes: Evidence from Ti and Like Metals
论文作者
论文摘要
当前对钝化的矛盾理解来自过度复杂的被动模型，缺陷的表征和错位的理论方法。从全新的实验中，我们发现Ti被动膜具有空间序列的宏观结构。一开始，立即形成热力学稳定的化学吸附的Ti-O单层，以使大多数Ti原子失活，并在金属基质上进行环境氧的直接反应，然后在TiOX@Ti Ceramet类似非平衡梯度层下方的下方迅速形成。这两层通过非线性氧化阻尼的非线性机理缓慢生长，以协同作用，以使宏观排序的被动膜生长缓慢生长，从而产生钝化。这些发现反驳了“钝化的吸附理论”和“被动膜理论”，并告知我们称为“增量氧化阻尼的钝化理论”的新理论。
Current contradictory understanding of passivation comes from overly-complex passive models, defective characterization and misplaced theoretical approaches. From brand-new experimentation, we find that a Ti passive membrane has spatiotemporally-ordered macrostructure. At the start, a thermodynamically-stable chemisorbed Ti-O monolayer is immediately formed to inactivate the outmost Ti atoms and shield direct reaction of environmental oxygens on metallic matrix, and then an underneath TiOx@Ti ceramet-like non-equilibrium gradient oxide layer rapidly forms. The two layers work synergistically to keep the macro-ordered passive membrane growing slowly via non-linear mechanism of incremental oxidation damping, thus effecting passivation. These findings disprove "the adsorption theory of passivation" and "the theory of passivity film" and inform a new theory we call "passivation theory of incremental oxidation damping".
