论文标题
范德华过渡金属Trihalides中的晶体结构演变
Crystal structure evolution in the van der Waals transition metal trihalides
论文作者
论文摘要
大多数过渡金属三亚甲化体是二态的。基于铬的三合会,CRCL3,CRBR3,CRI3的特征是低温期采用了三角bii3类型,而高温相的结构是ALCL3类型的单斜型(C2/m)。两个晶体学阶段之间的结构过渡是一阶类型的,在CRCL3和CRI3中具有较大的热滞后。我们通过测量特定的热量,磁化和X射线衍射作为温度的功能并观察到的反向情况,研究了基于钒的对应物VCL3,VBR3和VI3的晶体结构和结构相变。在这些情况下,高温相具有较高的对称性,而低温结构则揭示了较低的对称性。与CRX3相比,它们之间的结构相变表现没有可测量的滞后。讨论了V和CR Trihalides中晶体结构类型的比率C/A演变的可能关系。
Most transition-metal trihalides are dimorphic. The representative chromium-based triad, CrCl3, CrBr3, CrI3, is characterized by the low-temperature phase adopting the trigonal BiI3 type while the structure of the high-temperature phase is monoclinic of AlCl3 type (C2/m). The structural transition between the two crystallographic phases is of the first-order type with large thermal hysteresis in CrCl3 and CrI3. We studied crystal structures and structural phase transitions of vanadium-based counterparts VCl3, VBr3, and VI3 by measuring specific heat, magnetization, and X-ray diffraction as functions of temperature and observed an inverse situation. In these cases, the high-temperature phase has a higher symmetry while the low-temperature structure reveals a lower symmetry. The structural phase transition between them shows no measurable hysteresis in contrast to CrX3. Possible relations of the evolution of the ratio c/a of the unit cell parameters, types of crystal structures, and nature of the structural transitions in V and Cr trihalides are discussed.