论文标题

高导电电荷传输层损害薄膜太阳能电池中的电荷提取性选择性

Highly conductive charge transport layers impair charge extraction selectivity in thin-film solar cells

论文作者

Nyman, Mathias, Ahläng, Christian, Dahlström, Staffan, Pranav, Manasi, Benduhn, Johannes, Qudsia, Syeda, Smått, Jan-Henrik, Spoltore, Donato, Österbacka, Ronald

论文摘要

电荷选择性中间层在薄膜光伏电池中至关重要,例如有机和钙钛矿太阳能电池。电荷运输层(掺杂和未掺杂)可能构成了最重要的电荷选择性层中的类别;但是,尚不清楚如何设计电荷运输层,以确保在阻止少数载体的同时有效提取多数载体。这项工作阐明了与多数载体电导率不同的电荷运输层的良好层。我们通过线性增加电压技术使用电荷提取,以确定模型系统设备中少数载流子的表面重组速度,其运输层中多数载体电导率变化。我们的结果表明,大多数载体的传输层不会阻止少数载流子 - 至少在内置电压附近或更高的工作电压下,由于直接在运输层吸收层层面界面上直接双分子重组。我们此外,讨论并提出了设计原理,以使用电荷传输层在薄膜太阳能电池中实现选择性电荷提取。

Charge selective interlayers are crucial in thin-film photovoltaics, such as organic and Perovskite solar cells. Charge transporting layers (doped and undoped) constitute perhaps the most important class of charge selective interlayers; however, it is not well understood how a charge transporting layer should be designed in order to ensure efficient extraction of majority carriers while blocking minority carriers. This work clarifies how well charge-transporting layers with varying majority carrier conductivities block minority carriers. We use the Charge Extraction by a Linearly Increasing Voltage technique to determine the surface recombination velocity of minority carriers in model system devices with varying majority carrier conductivity in the transporting layer. Our results show that transporting layers with high conductivity for majority carriers do not block minority carriers - at least not at operating voltages close to or above the built-in voltage, due to direct bi-molecular recombination across the transporting layer-absorber layer interface. We furthermore discuss and propose design principles to achieve selective charge extraction in thin film solar cells using charge transporting layers.

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