论文标题

AGCL诱导的热盐应激腐蚀在钛合金中开裂

AgCl-induced hot salt stress corrosion cracking in a titanium alloy

论文作者

Shi, Yitong, Joseph, Sudha, Saunders, Edward A., Sandala, Rebecca S., Walker, Adrian, Lindley, Trevor C., Dye, David

论文摘要

在\ si {500} {\ mega \ pascal}和\ si {380} {\ celsius} {\ si {24} {24} {\ si} {\ si {\ celsius} {24} {\ si} {\ si {\ celsius} {\ si {24} {\ si} {\ si {\ si} {\ si {\ celsius} {24} {\ hour}的暴露。 SEM和STEM-EDX检查FIB截面的水泡和裂纹,表明金属Ag是形成并沿裂纹迁移的。 TEM分析还揭示了\ ce {sno2}和\ ce {al2o3}腐蚀产物混合到\ ce {tio2}中。断裂表面具有跨粒性质,在主要$α$相中具有脆性外观。在裂解裂解的主要$α$晶粒中观察到长,直和非相互作用的位错,具有基础和金字塔痕迹。这与开裂机理的脱位发射视图一致。

The mechanism of AgCl-induced stress corrosion cracking of Ti-6246 was examined at \SI{500}{\mega\pascal} and \SI{380}{\celsius} for \SI{24}{\hour} exposures. SEM and STEM-EDX examination of a FIB-sectioned blister and crack showed that metallic Ag was formed and migrated along the crack. TEM analysis also revealed the presence of \ce{SnO2} and \ce{Al2O3} corrosion products mixed into \ce{TiO2}. The fracture surface has a transgranular nature with a brittle appearance in the primary $α$ phase. Long, straight and non-interacting dislocations were observed in a cleavage-fractured primary $α$ grain, with basal and pyramidal traces. This is consistent with a dislocation emission view of the the cracking mechanism.

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