论文标题
在离子导体和离子电容器的热电器上
On the thermopower of ionic conductor and ionic capacitors
论文作者
论文摘要
从理论上讲，我们研究离子导体对施加温度降低的热电响应。作为主要结果，我们发现有关电荷交换的开放和封闭系统，导致热电器的表达式不同，甚至可能具有相反的迹象。对于经验最相关的零电流稳态，我们表明，与金属和半导体所知道的相反，离子导体的热电器不取决于迁移率。离子和电子导体的不同行为可追溯到离子载体和电子 - 电子最好双的抗化剂。
We theoretically study the thermoelectric response of ionic conductors to an applied temperaturegradient. As a main result we find that open and closed systems with respect to charge exchange,result in different expressions for the thermopower which may even take opposite signs. For theexperimentally most relevant zero-current steady state, we show that the thermopower of ionic conductorsdoes not depend on the mobilities, contrary to what is known for metals and semiconductors.The different behavior of ionic and electronic conductors is traced back to the unlike conservationlaws for ionic carriers and electron-hole pairs.
