论文标题

使用合金纳米颗粒合成狭窄的SNTE纳米线

Synthesis of narrow SnTe nanowires using alloy nanoparticles

论文作者

Liu, Pengzi, Han, Hyeuk Jin, Wei, Julia, Hynek, David J., Hart, James L., Han, Myung Geun, Trimble, Christie J., Williams, James R., Zhu, Yimei, Cha, Judy J.

论文摘要

拓扑结晶绝缘子锡尿酸盐(SNTE)提供了一个丰富的操场来检查相关电子状态的相互作用,例如铁电性,拓扑表面状态和超导性。由于一维(1D)限制效应,使SNTE进入纳米线进一步引起了新的电子状态。因此,为了进行运输测量,必须使SNTE纳米线在直径上狭窄,以确保拓扑表面电子的1D限制和相干性。这项研究报告了一种轻松的生长方法,使用合金纳米颗粒作为生长催化剂产生高产量的狭窄SNTE纳米线。使用合金纳米颗粒生长的SNTE纳米线的平均直径为85 nm,使用金纳米颗粒作为生长催化剂,几乎比以前的平均直径为240 nm的平均直径降低了三倍。运输测量结果揭示了纳米线直径对残留抗性比和磁路震动的影响。特别是,观察到SNTE的铁电过渡温度随纳米线直径系统变化。透射电子显微镜中狭窄的SNTE纳米线的原位低温冷却直接揭示了与铁电跃迁相关的菱形结构过渡。因此,这些狭窄的SNTE纳米线代表了一个模型系统,用于研究由1D限制引起的电子状态,例如1D拓扑超导性以及潜在的多波段超导性。

Topological crystalline insulator tin telluride (SnTe) provides a rich playground to examine interactions of correlated electronic states, such as ferroelectricity, topological surface states, and superconductivity. Making SnTe into nanowires further induces novel electronic states due to one-dimensional (1D) confinement effects. Thus, for transport measurements, SnTe nanowires must be made narrow in their diameters to ensure the 1D confinement and phase coherence of the topological surface electrons. This study reports a facile growth method to produce narrow SnTe nanowires with a high yield using alloy nanoparticles as growth catalysts. The average diameter of the SnTe nanowires grown using the alloy nanoparticles is 85 nm, nearly a factor of three reduction from the previous average diameter of 240 nm using gold nanoparticles as growth catalysts. Transport measurements reveal the effect of the nanowire diameter on the residual resistance ratio and magnetoresistance. Particularly, the ferroelectric transition temperature for SnTe is observed to change systematically with the nanowire diameter. In situ cryogenic cooling of narrow SnTe nanowires in a transmission electron microscope directly reveals the cubic to rhombohedral structural transition, which is associated with the ferroelectric transition. Thus, these narrow SnTe nanowires represent a model system to study electronic states arising from the 1D confinement, such as 1D topological superconductivity as well as a potential multi-band superconductivity.

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