论文标题
（15-Crown-5）BII $ _3 $作为卤素粘合超分子骨料的基础
(15-crown-5)BiI$_3$ as a Building Block for Halogen Bonded Supramolecular Aggregates
论文作者
论文摘要
我们介绍了（15-Crown-5）BII $ _3 $（1）和（15克罗恩5）BII $ _3 $*0.5TIE（2）的综合和表征，这是一种带有Tetraiodoodoododoethelene（tie）的卤素键合载体，一种典型的Halogen Bond供体。我们的结果表明，主要组金属卤化物的冠状醚复合物可以用作卤素键受体的合成新超分子骨料，并强调了两个构件之间的显着相互作用。
We present the synthesis and characterization of (15-crown-5)BiI$_3$ (1) and (15-crown-5)BiI$_3$*0.5TIE (2), a halogen bonded adduct with tetraiodoethylene (TIE), a typical halogen bond donor. Our results show that crown ether complexes of main group metal halides can be employed as halogen bond acceptors for the synthesis of new supramolecular aggregates and highlight the significant interaction between the two building blocks.
