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Ab initio calculations of bulk nuclear properties (ground-state energies, root mean square charge radii and charge density distributions) are presented for seven complete isotopic chains around calcium, from argon to chromium. Calculations are performed within the Gorkov self-consistent Green's function approach at second order and make use of two state-of-the-art two- plus three-nucleon Hamiltonians, $NN$+$3N\text{(lnl)}$ and NNLO$_{\text{sat}}$. An overall good agreement with available experimental data is found, in particular for differential energies (charge radii) when the former (latter) interaction is employed. Remarkably, neutron magic numbers $N=28,32,34$ emerge and evolve following experimental trends. In contrast, pairing gaps are systematically underestimated. General features of the isotopic dependence of charge radii are also reproduced, as well as charge density distributions. A deterioration of the theoretical description is observed for certain nuclei and ascribed to the inefficient account of (static) quadrupole correlation in the present many-body truncation scheme. In order to resolve these limitations, we advocate the extension of the formalism towards incorporating breaking of rotational symmetry or, alternatively, performing a stochastic sampling of the self-energy.