论文标题
通过奇迹分析的12C14N实验能水平
Experimental energy levels of 12C14N through MARVEL analysis
论文作者
论文摘要
Cyano自由基（CN）是许多天文学和化学派别中的关键分子。使用\ Marvel {}（测量的主动旋转振动能水平）算法确定8个双重CN的doblet状态的准确，经验的Rovibronic能级。 \ notrans {}过渡已从\ nosources {}不同的已发布来源验证，以生成\ noenergy {}自旋 - 旋转能量水平。将从\ Marvel {}分析获得的经验能级与\ Mollist {}行列表的当前能级进行比较。 \ mollist {}过渡频率使用\ marvel {}能量级数据更新，该数据将通过实验数据获得的频率从原始的11.3 \％中获得\ arter {77.3 \％}，从92.6 \％的转移中，具有在10 $^{-23} $ cm/morec的强度的92.6 \％的转移中，at-23} $ cm/morec/morec/morec/morec/morec at at at at at at in vartion {77.3 \％}。在2000 K时，仅使用\ marvel {}能级恢复了分区功能的100.0 \％，而98.2 \％仍在5000 K处恢复。
The cyano radical (CN) is a key molecule across many different factions of astronomy and chemistry. Accurate, empirical rovibronic energy levels with uncertainties are determined for 8 doublet states of CN using the \Marvel{} (Measured Active Rotational-Vibrational Energy Levels) algorithm. \notrans{} transitions were validated from \nosources{} different published sources to generate \noenergy{} spin-rovibronic energy levels. The empirical energy levels obtained from the \Marvel{} analysis are compared to current energy levels from the \Mollist{} line list. The \Mollist{} transition frequencies are updated with \Marvel{} energy level data which brings the frequencies obtained through experimental data up to \alert{77.3\%} from the original 11.3\%, with 92.6\% of the transitions with intensities over 10$^{-23}$ cm/molecule at 1000 K now known from experimental data. At 2000 K, 100.0\% of the partition function is recovered using only \Marvel{} energy levels, while 98.2\% is still recovered at 5000 K.
