论文标题
在集群磁铁Limoo2中稳健的原子轨道
Robust atomic orbital in the cluster magnet LiMoO2
论文作者
论文摘要
在这项研究中，我们提出了与金红石相关的材料limoo2，该材料变成簇磁体，并在冷却后在预形成的钼二聚体上表现出旋转的单线形成。与普通的簇磁体不同，尽管形成了分子轨道，但原子dyz轨道稳健地生存，从而影响所选材料的磁性。这种具有分子和原子轨道特征的混合簇磁体在孤立的簇上实现了多个独立的自旋，从而导致了研究孤立的自旋二聚体物理学的理想平台。
In this study, we present a rutile-related material, LiMoO2, that becomes a cluster magnet and exhibits a spin singlet formation on a preformed molybdenum dimer upon cooling. Unlike ordinary cluster magnets, the atomic dyz orbital robustly survives despite the formation of molecular orbitals, thereby affecting the magnetic properties of the selected material. Such hybrid cluster magnets with the characters of molecular and atomic orbitals realize multiple independent spins on an isolated cluster, leading to an ideal platform to study the isolated spin dimers physics.
