论文标题

刺激反应性聚合物刷中的压力

Stress in a stimuli-responsive polymer brush

论文作者

Manav, M., Ponga, M., Phani, A. Srikantha

论文摘要

聚合物刷在感应,驱动,自我折叠等方面的应用急性取决于刷子压力引起的刷子移植底物的可调弯曲。但是,尚未研究刺激响应刷中的压力。在这项工作中,我们使用强伸拉伸理论(SST)研究了中性水溶性聚合物的刺激反应性平面聚合物刷的应力。首先,将聚合物链的langevin力扩展关系的SST扩展到刺激反应刷的研究。然后,使用扩展的SST和经验弗洛里 - 猎人参数获得了聚(N-异丙基酰胺)(PNIPAM)刷的应力曲线和其他特性。该模型预测,PNIPAM刷中的应力在所有温度和移植密度下都是不均匀的和压缩的。预计随着移植密度的增加,预计所得应力会增加。此外,在低移植物密度刷中平稳之前,它随着温度的升高而降低。相反,在高密度刷中温度随温度的升高时,其幅度较弱。这种对比行为可追溯到相互作用的自由能密度\ emph \ emph {vs}聚合物体积分数曲线,用于较大的体积分数,以及由于有限的可扩展性而导致的链条加固。此外,我们的结果表明,通过变化随着移植密度降低而调节所得应力的能力。

The application of a polymer brush in sensing, actuation, self-folding, among others acutely depends on the tuneable bending of a brush-grafted substrate caused by the stress in the brush. However, the stress in a stimuli-responsive brush has not been investigated. In this work, we study the stress in the stimuli-responsive planar polymer brushes of neutral water-soluble polymers with low to very high graft densities using strong stretching theory (SST). First, SST with the Langevin force-extension relation for a polymer chain is extended to the study of stimuli-responsive brushes. Stress profile and other properties of a Poly(N-isopropylacrylamide) (PNIPAm) brush are then obtained using the extended SST and an empirical Flory-Huggins parameter. The model predicts that the stress in a PNIPAm brush is inhomogeneous and compressive at all temperatures and graft densities. The resultant stress is predicted to increase in magnitude with increasing graft density. Moreover, it decreases in magnitude with an increase in temperature before plateauing in low graft density brushes. In contrast, its magnitude increases weakly with increasing temperature in high density brushes. This contrasting behavior is traced to the minimum in interaction free energy density \emph{vs} polymer volume fraction curve for PNIPAm solution at a large volume fraction, and stiffening of chains due to finite extensibility. Furthermore, our results indicate that the ability to tune the resultant stress by changing temperature diminishes with increasing graft density.

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