论文标题
SP $^2 $固体碳的无定形状态
Amorphous state of sp$^2$ solid carbon
论文作者
论文摘要
碳原子的两模式价电子构型奠定了独特的两种模式无定形状态的基础。从固态物理学的基本原理中,SP $^3 $和SP $^2 $无形的碳是两个不同的非晶子物种,其特征在概念上不同的短距离订单,即四面体结合的SP3配置的原子和尺寸限制的SP $^2 $ Chapeene域与HeteroatoM构成了HeteroatoM项链。 Sp $^2 $非态的分子特征与强制碎片的适当情况下实心无态性的反应机理相一致。
Two-mode valence electron configuration of carbon atoms lays the foundation of the unique two-mode amorphous state of the monoatomic carbon solid. From the fundamentals of solid-state physics, sp$^3$ and sp$^2$ amorphous carbons are two different amorphous species characterized by conceptually different short-range orders, namely, groups of tetrahedrally bonded sp3 configured atoms and size-restricted sp$^2$ graphene domains framed with heteroatom necklaces. Molecular character of sp$^2$ amorphics is coherent with the reaction mechanism of the solid amorphicity in due course of the forced fragmentation.