论文标题

在银固态易碎过程中监测形态和化学特性

Monitoring morphological and chemical properties during silver solid-state dewetting

论文作者

Berni, M., Carrano, I., Kovtun, A., Russo, A., Visani, A., Dionigi, C., Liscio, A., Valle, F., Gambardella, A.

论文摘要

银薄膜中的固态脱水现象提供了一种直接的方法,可以获得具有控制形状或尺寸的结构 - 后者原则上跨越了几个幅度 - 对许多涉及高科技行业和生物医学氨酸的应用具有潜在的兴趣。在这项工作中,纳米结构的银通过脉冲电子消融技术沉积,其表面在温度升高时在空气中进行热处理。然后,通过X射线光发射光谱和原子力显微镜同时监测表面化学和形态。特别是,表面高度的功率光谱密度用于分析退火引起的形态的改变。结果表明,该方法添加了有关侵蚀过程的一定程度的信息,因为它允许在长距离和短距离表面行为之间进行分开,并检索与应用程序有关功能的描述相关的统计数量。我们的结果是在多学科方法的框架内提出的,其优势和限制得到了加深和讨论。

Solid-state dewetting phenomenon in silver thin films offers a straightforward method to obtain structures having controlled shape or size -this latter in principle spanning several orders of magnitudes -- with potentially strong interest in many applications involving high-tech industry and biomedicine. In this work nanostructured silver is deposited by pulsed electron ablation technique and its surface modified upon thermal treatments in air at increasing temperatures. Surface chemistry and morphology are then monitored simultaneously by X-ray photoemission spectroscopy and atomic force microscopy; in particular, the power spectral density of surface heights is used to analyze the alteration of morphology induced by annealing. It is shown that this approach adds a level of information about the dewetting process since it allows to separate between long- and short-range surface behavior and to retrieve statistical quantities relevant to a description of the features in view of applications. Our results are presented in the framework of a multidisciplinary approach, advantages and limits of which are deepened and discussed.

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