论文标题

转向炔烃与地表合成催化剂的同构

Steering alkyne homocoupling with on-surface synthesized catalysts

论文作者

Mohammed, Mohammed S. G., Colazzo, Luciano, Gallardo, Aurelio, Pomposo, José A., Jelínek, Pavel, de Oteyza, Dimas G.

论文摘要

我们报告了一个多步骤的地面合成策略。第一步是金属有机络合物的表面支撑合成,随后将其用作催化剂来转向表面炔烃偶联反应。此外,我们分析和比较获得的不同耦合基序的电子特性。

We report a multi-step on-surface synthesis strategy. The first step consists in the surface-supported synthesis of metal-organic complexes, which are subsequently used as catalysts to steer on-surface alkyne coupling reactions. In addition, we analyze and compare the electronic properties of the different coupling motifs obtained.

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