论文标题

评论“广义鲍尔茨曼分布是吉布斯 - 香农熵等于热力学熵的唯一分布”,X。Gao,E。Gallicchio和A.E. Roitberg [J.化学物理。 151,034113(2019)]

Comment on "The generalized Boltzmann distribution is the only distribution in which the Gibbs-Shannon entropy equals the thermodynamic entropy" by X. Gao, E. Gallicchio and A.E. Roitberg [J. Chem. Phys. 151, 034113 (2019)]

论文作者

Gujrati, P. D.

论文摘要

本文的标题导致了不正确的结论,因为我们表明本文的平衡结果是文献中已经可用的内部平衡中非平衡系统的一般结果的特殊限制。我们还指出了作者采取的方法的一些局限性。

The title of the paper leads to an incorrect conclusion as we show that the equilibrium result of the paper is a special limit of a general result for nonequilibrium systems in internal equilibrium already available in the literature. We also point out some of the limitations of the approach taken by the authors.

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