论文标题

酮 - 烯醇互变异稳定在AU上驱动leucoquinizarin的自组装(111)

Keto-enol tautomerization drives the self-assembly of Leucoquinizarin on Au(111)

论文作者

Costantini, Roberto, Colazzo, Luciano, Batini, Laura, Stredansky, Matus, Mohammed, Mohammed S. G., Achilli, Simona, Floreano, Luca, Fratesi, Guido, de Oteyza, Dimas G., Cossaro, Albano

论文摘要

表现出来的leucquinizarin分子(111)表面上的自组装的特征是分子主要以其酮 - 亚元素形式形式为特征,其临时切换到其他互变体形式的证据。这揭示了组装分子的亚稳定化学性质,被认为是在形成更复杂的异质有机界面中的可能就业

The self-assembly of Leucoquinizarin molecule on Au(111) surface is shown to be characterized by the molecules mostly in their keto-enolic tautomeric form, with evidences of their temporary switching to other tautomeric forms. This reveals a metastable chemistry of the assembled molecules, to be considered for their possible employment in the formation of more complex hetero-organic interfaces

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