论文标题

颗粒间相互作用对两个物种纳米通道传输热力学的影响

Impact of Interparticle Interaction on Thermodynamics of Nano-Channel Transport of Two Species

论文作者

Bauer, Wolfgang Rudolf

论文摘要

我们在随机热力学框架内提出了两种物种通道传输的严格数学方法,该方法解释了颗粒间相互作用的影响。与平均场方法不同,该模型通过考虑通道的职业状态之间的随机过渡来明确保存空间相关性。粒子间相互作用决定了布朗棘轮,例如整流力,这些物种相互互相施加。同一物种的颗粒之间的一个吸引人的空通道和强烈的排斥力出现了完美的运输耦合。然后将随机过渡局限于带有圆形拓扑的子空间,这使得两种物种的通道流相当。对于相反的浓度梯度,这使得该物种具有更强的梯度,驱动端的熵产生一个,另一种是驱动的,并产生负熵。与一个物种的颗粒中的差异相互作用的差异相互作用,但是维持这种相互作用的其他物种,为该圆形子空间增加了旁路路径。在这条路径上,出现了较少排斥的粒子间相互作用的物种的泄漏流,该物种与其浓度梯度平行,因此产生阳性熵。现在,适当的强对方浓度梯度可以同时使各自物种的流动平行,这使每个物种都会产生阳性熵。该物种具有搭桥式选项的纠正潜力减少,这意味着存在其他物种的梯度,其流量和梯度始终是平行的。相反,较不耦合物种的流动可能总是会通过另一个梯度的足够强对方梯度对其梯度进行反平行。

We present a rigorous mathematical approach of two species channel transport within the framework of stochastic thermodynamics, which explains the impact of interparticle in-channel interactions. Different from mean field approaches, the model explicitly conserves spatial correlations by considering stochastic transitions between the channel's occupation states. The interparticle interactions determine the Brownian ratchet like rectifying forces, which these species exert mutually on each other. Perfect coupling of transport emerges by an attractive empty channel and strong repulsive forces between particles of the same species. Stochastic transitions are then confined to a subspace with circular topology, which makes channel flows of both species become equivalent. For opposing concentration gradients, this makes the species with the stronger gradient the driving, positive entropy producing one, the other is driven and produces negative entropy. A differential interaction with less repulsive forces within particles of one species, but maintenance of this interaction for the other species, adds a bypass path to this circular subspace. On this path a leak flow of the species with less repulsive interparticle interaction emerges, which is directed parallel to its concentration gradient, and, hence, produces positive entropy. Now, appropriate strong opposing concentration gradients may simultaneously parallelize flow of their respective species, which makes each species produce positive entropy. The rectifying potential of the species with the bypass option is diminished, which implies the existence of a gradient of the other species, above which its flow and gradient are always parallel. Conversely flow of the less coupled species may always be turned anti-parallel to its gradient by a sufficient strong opposing gradient of the other one.

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