论文标题

polycrystalline散装SR $ _3 $ oso $ _6 $ double-perovskite绝缘子的研究:与1000 k铁磁上皮膜进行比较

Study of polycrystalline bulk Sr$_3$OsO$_6$ double-perovskite insulator: comparison with 1000 K ferromagnetic epitaxial films

论文作者

Chen, Jie, Feng, Hai L., Matsushita, Yoshitaka, Belik, Alexei A., Tsujimoto, Yoshihiro, Tanaka, Masahiko, Chung, Duck Young, Yamaura, Kazunari

论文摘要

PolyCrystalline SR $ _3 $ OSO $ _6 $,是订购的双重植物绝缘子,在高温和高压条件下通过固态反应合成1200 $^\ circe $ c和6 GPA。该合成使我们能够对SR $ _3 $ _3 $ oso $ _6 $的大量形式进行比较研究,以揭示1000 K铁磁性的驾驶机制,最近发现了该驱动器机制,该机构是针对外在生长的SR $ $ _3 $ _3 $ oso $ _6 $ _6 $电影的。与电影不同,批量是由反铁磁性而不是铁磁性主导的。因此,仅当Sr $ _3 $ oso $ _6 $在接口的影响下时,才出现强大的铁磁顺序。在低温下找到39.6(9)10 $^{ - 3} $ j mol $^{ - 1} $ j mol $^{ - 1} $的特定热容量在低温下($ <$ 17 K)。该值非常高,表明在磁接地状态下可能存在可能的费米样激发。尽管SR $ _3 $ OSO $ _6 $的散装和胶片形式共享相同的晶格基础和电绝缘状态,但它们之间的磁性完全不同。

Polycrystalline Sr$_3$OsO$_6$, which is an ordered double-perovskite insulator, is synthesized via solid-state reaction under high-temperature and high-pressure conditions of 1200 $^\circ$C and 6 GPa. The synthesis enables us to conduct a comparative study of the bulk form of Sr$_3$OsO$_6$ toward revealing the driving mechanism of 1000 K ferromagnetism, which has recently been discovered for epitaxially grown Sr$_3$OsO$_6$ films. Unlike the film, the bulk is dominated by antiferromagnetism rather than ferromagnetism. Therefore, robust ferromagnetic order appears only when Sr$_3$OsO$_6$ is under the influence of interfaces. A specific heat capacity of 39.6(9) 10$^{-3}$ J mol$^{-1}$ K$^{-2}$ is found at low temperatures ($<$17 K). This value is remarkably high, suggesting the presence of possible fermionic-like excitations at the magnetic ground state. Although the bulk and film forms of Sr$_3$OsO$_6$ share the same lattice basis and electrically insulating state, the magnetism is entirely different between them.

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