论文标题
电子梁诱导的纳米孔中的Bernal堆叠六角硼硝酸盐
Electron Beam-Induced Nanopores in Bernal-Stacked Hexagonal Boron Nitride
论文作者
论文摘要
在二维材料中控制纳米孔的大小和形状是在人工原子中的DNA测序,筛分和量子发射等应用中的关键挑战。我们在这里使用高能电子束在(非常规)的Bernal堆叠AB-H-BN(非常规)的Bernal堆叠AB-H-BN进行了实验和理论上的三角空缺研究。由于AB-H-BN的几何构型,将不同层中的三角形孔排列在一起,并且它们的尺寸受电子照射的持续时间的控制。与更常见的AA'BN BN中发生的情况相反,空置边缘处的共价键合在空缺边缘不受欢迎。在高分辨率的透射电子显微镜中观察到了多种双层AB-H-BN中的单层,同心和双层孔,并使用Ab ITIOL模拟进行了表征。 AB-H-BN中的双层孔通常形成,并且在不打破双层特征的情况下生长。 AB-H-BN中的纳米孔具有广泛的电子特性,范围从半金属到非磁性和磁性半导体。因此,由于孔径的可控性,电子结构在这些系统中也可以高度控制,并且有可能针对特定的应用调整。
Controlling the size and shape of nanopores in two-dimensional materials is a key challenge in applications such as DNA sequencing, sieving, and quantum emission in artificial atoms. We here investigate experimentally and theoretically triangular vacancies in (unconventional) Bernal-stacked AB-h-BN formed using a high-energy electron beam. Due to the geometric configuration of AB-h-BN, triangular pores in different layers are aligned, and their sizes are controlled by the duration of the electron irradiation. Interlayer covalent bonding at the vacancy edge is not favored, as opposed to what occurs in the more common AA'-stacked BN. A variety of monolayer, concentric and bilayer pores in bilayer AB-h-BN are observed in high-resolution transmission electron microscopy and characterized using ab initio simulations. Bilayer pores in AB-h-BN are commonly formed, and grow without breaking the bilayer character. Nanopores in AB-h-BN exhibit a wide range of electronic properties, ranging from half-metallic to non-magnetic and magnetic semiconducting. Therefore, because of the controllability of the pore size, the electronic structure is also highly controllable in these systems, and can potentially be tuned for particular applications.