论文标题

剪切诱导的bidisperse和polyDisperse聚合物混合物中的解散:来自多流体模型的预测

Shear Induced Demixing in Bidisperse and Polydisperse Polymer Blends: Predictions From a Multi-Fluid Model

论文作者

Peterson, Joseph D., Fredrickson, Glenn H., Leal, L. Gary

论文摘要

鉴于二散和多分散纠缠的线性聚合物的构成模型的最新进展,我们为经典的两流体近似近似不均匀聚合物混合物流提供了新的多流体概括。作为模型的应用,我们考虑对剪切诱导的分解(SID)不稳定性的线性和非线性动力学的预测,并在与分子分子和对数正常的分子量分布的混合物中进行预测。我们发现,即使在组件链之间没有任何化学对比度的情况下,如果两个链的尺寸有足够的对比,则施加的流量也会引起解散的不稳定性。 SID的下限多分散性与链条之间的弹性力(每件纠缠)(例如,多分散指数减去一个)超出熵力(每链kt)超过熵力。对于Bi-Disperse混合物,我们表明SID的非线性动力学强烈类似于纠缠聚合物溶液中SID的以前显示的内容。

In light of recent advancements in the constitutive modelling of bidisperse and polydisperse entangled linear polymers, we present a new multi fluid generalization of the classic two fluid approximation for flows of inhomogeneous polymer blends. As an application of the model, we consider predictions for the linear and nonlinear dynamics of shear induced demixing (SID) instabilities in blends with bidisperse and lognormal molecular weight distributions. We find that even in the absence of any chemical contrast between component chains, an imposed flow can induce a demixing instability provided there is sufficient contrast in the size of the two chains. The lower bound polydispersity for SID coincides with the point where elastic forces (kT per entanglement) scaled by the contrast between chains (e.g. polydispersity index minus one) exceed the entropic forces for mixing (kT per chain). For bi-disperse blends, we show that the non-linear dynamics of SID strongly resemble what has previously been shown for SID in entangled polymer solutions.

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