论文标题

硬血小板悬浮液中簇的形状,连接性渗透和电导率

Shape, connectedness percolation and electrical conductivity of clusters in suspensions of hard platelets

论文作者

Atashpendar, Arshia, Ingenbrand, Tim, Schilling, Tanja

论文摘要

使用Monte Carlo模拟,我们研究了硬导电血小板悬浮液中的几何渗透和电导率如何受到血小板的添加及其自发比对程度的影响。对于宽高比$ 10、25美元和$ 50 $,我们一贯观察到渗透阈值的单调降低,这是体积分数的函数。在列中阶段,渗透簇内部粒子的分布在球体上变少,簇的纵横比增加。然而,尽管它们的长宽比仍然是体积分数的函数,但簇在各向同性相中也是各向异性的。将血小板的渗透簇映射到线性电阻网络,并将单位电导分配给所有连接,我们在各向同性纽扣过渡和各个稳定相之间都发现了恒定的电导率。这种行为与网络的其他观察到的拓扑特性一致。相反,使用各向异性电导模型,网络电导率随各向同性的体积分数的增加而降低,并在夜间发作时进一步减少。因此,我们的观察结果一致地表明,与棒状填充剂不同,血小板悬浮液产生的网络结构既不非常敏感颗粒纵横比也不对对齐,从而使血小板在导电复合材料中的分散剂较小。

Using Monte Carlo simulations, we investigate how geometric percolation and electrical conductivity in suspensions of hard conducting platelets are affected by the addition of platelets and their degree of spontaneous alignment. For aspect ratios $10, 25$ and $50$, we consistently observe a monotonically decreasing percolation threshold as a function of volume fraction. In the nematic phase, the distribution of particles inside the percolating clusters becomes less spherically symmetric and the aspect ratio of the clusters increases. However, the clusters are also anisotropically shaped in the isotropic phase, although their aspect ratio remains constant as a function of volume fraction. Mapping the percolating clusters of platelets to linear resistor networks, and assigning unit conductance to all connections, we find a constant conductivity both across the isotropic-nematic transition and in the respective stable phases. This behaviour is consistent with the other observed topological properties of the networks. On the contrary, using an anisotropic conductance model, the network conductivity decreases with increasing volume fraction in the isotropic, and further diminishes at the onset of the nematic. Hence, our observations consistently suggest that unlike for rod-like fillers, the network structures that arise from platelet suspensions are neither very sensitive to the particle aspect ratio nor to alignment, thus rendering platelets less versatile fillers for dispersion in conductive composites.

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